Microwave spectrum of trans, gauche, trans-propyl nitrite.
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چکیده
منابع مشابه
The Microwave Spectrum of trans-2,3-E>imethyloxirane in Torsional Excited States
The microwave spectrum of trans-2,3-dimethyloxirane ( C H 3 C H O C H C H 3 ) in the excited torsional states u17 = 1 and vi3 — 1 has been measured in the range from 8 to 26 G H z and assigned. An analysis of internal rotat ion splittings of the observed rotational transitions was performed using the internal axis method (or "combined axis method") with a newly developed program accounting for ...
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The effect of solvation and confinement on the conformational equilibria and kinetics of n-butane is examined using molecular dynamics simulations of the bulk and confined fluids and compared to appropriately chosen reference states. Clear evidence for a solvent shift of the preferred conformation in bulk n-butane is found. At a temperature of 292 K and a density of 6.05 nm-3 a small solvent sh...
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Density Functional Theory (DFT) calculations have been performed on the TTC-->TTT isomerization reaction of the open forms of the 1',3'-dihydro-8-bromo-6-nitro-1',3',3'-trimethylspiro[2H-1-benzopyran-2,2'-(2H)indole (8-Br-6-nitro-BIPS) system. The calculations were carried out in vacuo and in methylene chloride solution at different temperatures. Results are compared with the available experime...
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Tunable diode laser spectra of n-butane gas were recorded in the 740 cm 1 CH2-rocking region using path lengths of typically 300 m, pressures below 1 mbar and temperatures between 170 and 300 K. The spectra are complicated by the overlap of the two trans and gauche rotameric fundamentals, and by a strong absorption background probably caused by the addition of hot-band transitions involving exc...
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The rotational spectrum of trans-cinnamaldehyde ((E)-3-phenyl-2-propenal, C9H8O) was recorded by chirped-pulse Fourier transform microwave spectroscopy in the frequency range of 2-8.5 GHz. The odourant molecule is the essential component of cinnamon oil and causes the characteristic smell. The rotational signatures of two conformers were observed: s-trans-trans- and s-cis-trans-cinnamaldehyde. ...
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ژورنال
عنوان ژورنال: NIPPON KAGAKU KAISHI
سال: 1985
ISSN: 2185-0925,0369-4577
DOI: 10.1246/nikkashi.1985.1519